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“devout” in Latin

The English word devout itself goes back to Latin voveō, through dēvōtus.

Riddle & Arnold A Copious and Critical English–Latin Lexicon, 1864

devout
*rebus sacris intentus (attentive to the service of God, to prayer); *pietatis studio deditus: Deum reverens (fearing God): pius, religiosus (pious, religious): a devout prayer, ardentes preces: a devout heart, animus pius or Dei studiosus.

Quick answer

What is the Latin word for devout?
The usual Latin words for “devout” are pius, religiōsus. The right choice depends on the sense; see the distinctions below.

Entry from J. E. Riddle & T. K. Arnold, A Copious and Critical English–Latin Lexicon (rev. C. Anthon, New York: Harper, 1864), digitised by Fergus J. P. Walsh, CC BY-SA 4.0; Latin markup adapted by latindictionary.co.